Determination of reactivity ratios for ethylene/α‐olefin copolymerization catalysed by the C 2 H 4 [Ind] 2 ZrCl 2 /methylaluminoxane system | Zendy

Galland Griselda Barrera | Zendy; Quijada Paul | Zendy; Mauler Raquel Santos | Zendy; de Menezes Sônia C. | Zendy

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Determination of reactivity ratios for ethylene/α‐olefin copolymerization catalysed by the C 2 H 4 [Ind] 2 ZrCl 2 /methylaluminoxane system

Author(s) -

Galland Griselda Barrera,

Quijada Paul,

Mauler Raquel Santos,

de Menezes Sônia C.

Publication year - 1996

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1996.030170901

Subject(s) - comonomer , methylaluminoxane , ethylene , copolymer , olefin fiber , reactivity (psychology) , polymer chemistry , chemistry , metallocene , propene , organic chemistry , catalysis , polymerization , polymer , medicine , alternative medicine , pathology

The present study reports values of reactivity ratios for ethylene/1‐hexene, ethylene/1‐octene and ethylene/1‐decene copolymerizations promoted by C 2 H 4 [Ind] 2 ZrCl 2 /MAO. The comonomer reactivities are markedly influenced by the number of carbon atoms of the α‐olefin. The ethylene/1‐decene copolymerization depends on the concentration of α‐olefin in the feed.

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