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Polymerization of styrenes carrying dendrons of the first, second and third generation
Author(s) -
Neubert Ingo,
AmoulongKirstein Evelin,
Schlüter A.Dieter,
Dautzenberg Herbert
Publication year - 1996
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.1996.030170804
Subject(s) - dendrimer , polymer chemistry , monomer , polymerization , styrene , polymer , third generation , materials science , living polymerization , polymer science , chemistry , copolymer , radical polymerization , computer science , composite material , telecommunications
The synthesis of styrene monomers 5 (G‐1,2,3) with Fréchet‐type dendrons of the first, second and third generation, and their radically initiated polymerization to result in high molecular weight dendrimers 6 (G‐1,2,3) are reported. First light‐scattering investigations using 6 (G‐2) show that this polymer is best described as a Gaussian chain.