(η 3 ‐allyl)palladium(II) catalysts for the addition polymerization of norbornene derivatives with functional groups | Zendy

Reinmuth Annette | Zendy; Mathew Joice P. | Zendy; Melia Jennifer | Zendy; Risse Wilhelm | Zendy

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(η 3 ‐allyl)palladium(II) catalysts for the addition polymerization of norbornene derivatives with functional groups

Author(s) -

Reinmuth Annette,

Mathew Joice P.,

Melia Jennifer,

Risse Wilhelm

Publication year - 1996

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1996.030170304

Subject(s) - norbornene , bicyclic molecule , palladium , catalysis , chemistry , polymer chemistry , polymerization , tetrafluoroborate , medicinal chemistry , ene reaction , addition polymer , methanol , organic chemistry , polymer , ionic liquid

Cycloaliphatic polyolefins with functional groups were prepared by the Pd(II)‐catalyzed addition polymerization of norbornene derivatives. Homo‐ and copolymers containing repeating units based on bicyclo[2.2.1] hept‐5‐en‐2‐ylmethyl decanoate ( endo/exo ‐ratio = 80/20), bicyclo[2.2.1]hept‐5‐ene‐2‐carboxylic acid methyl ester ( exo/endo = 80/20), bicyclo[2.2.1]hept‐5‐ene‐2‐methanol ( endo/exo = 80/20), and bicyclo[2.2.1]hept‐5‐ene‐2‐carboxylic acid (100% endo ) were prepared in 49–99% yields with {(η 3 ‐allyl)Pd(BF 4 )} and {(η 3 ‐allyl)Pd(SbF 6 )} as catalysts. The catalyst containing the hexafluoroantimonate ion was slightly more active than the tetrafluoroborate based Pd‐complex.

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