Synthesis of novel glycopeptide‐polyoxazoline block copolymers by direct coupling between living anionic and cationic polymerization systems | Zendy

Tsutsumiuchi Kaname | Zendy; Aoi Keigo | Zendy; Okada Masahiko | Zendy

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Synthesis of novel glycopeptide‐polyoxazoline block copolymers by direct coupling between living anionic and cationic polymerization systems

Author(s) -

Tsutsumiuchi Kaname,

Aoi Keigo,

Okada Masahiko

Publication year - 1995

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1995.030161007

Subject(s) - copolymer , cationic polymerization , glycopeptide , oxazoline , polymer chemistry , polymerization , living polymerization , chemistry , block (permutation group theory) , amino acid , polymer , materials science , organic chemistry , radical polymerization , catalysis , biochemistry , geometry , mathematics , antibiotics

A novel glycopeptide‐containing block copolymer, poly[ O ‐(tetra‐ O ‐acetyl‐β‐ D ‐glucopyranosyl)‐ L ‐serine]‐ block ‐poly(2‐methyl‐2‐oxazoline) ( 5 ), was synthesized by mutual termination of living polymerizations of a sugar‐substituted α‐amino acid N ‐carboxyanhydride (NCA) ( 1 ) and 2‐methyl‐2‐oxazoline ( 3 ). 5 was deacetylated to provide the glycopeptide‐polyoxazoline block copolymer, poly[ O ‐(β‐ D ‐glucopyranosyl)‐ L ‐serine]‐ block ‐poly(2‐methyl‐2‐oxazoline) ( 6 ).

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