Premium
Coordination Polymers Based on Amphiphilic Oligomeric Silsesquioxanes and Transition Metal Ions (Co 2 + , Ni 2+ ): Structure and Stimuli‐Responsive Properties
Author(s) -
Shevchenko Valery,
Bliznyuk Valery,
Gumenna Mariana,
Klimenko Nina,
Stryutsky Alexandr,
Wang Junlei,
Binek Christian,
Chernyakova Margarita,
Belikov Konstantin
Publication year - 2021
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.202170018
Subject(s) - nanoclusters , supramolecular chemistry , materials science , hydrogen bond , amphiphile , polymer , metal ions in aqueous solution , intermolecular force , polymer chemistry , ion , transition metal , superparamagnetism , metal , crystallography , nanotechnology , molecule , crystal structure , organic chemistry , chemistry , copolymer , magnetization , catalysis , magnetic field , composite material , metallurgy , physics , quantum mechanics
Back Cover : In article number 2100085 by Valery Shevchenko, Mariana Gumenna, and co‐workers, coordination polymers based on Co 2+ , Ni 2+ ions and amphiphilic oligomeric silsesquioxanes, containing various ratios of n‐octadecylurethane and carboxyl groups (OSS‐C 18 H 37 ‐x‐COOH‐y), form a hierarchical stimuli‐responsive supramolecular structure stabilized by a network of intermolecular hydrogen and coordination bonds. The system possesses superparamagnetic properties due to the formation of metal ion nanoclusters and can be reversibly modified by application of external magnetic field and/or moderate heat.