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Moisture‐Resistant and Mechanically Strong Polyimide‐Polymethylsilsesquioxane Hybrid Aerogels with Tunable Microstructure
Author(s) -
Xi Shuang,
Wang Xiaodong,
Liu Ting,
Zhang Ze,
Zhang Xiaoxue,
Shen Jun
Publication year - 2021
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.202000612
Subject(s) - materials science , methyltrimethoxysilane , microstructure , polyimide , aerogel , supercritical drying , thermal stability , composite material , polymer , chemical engineering , layer (electronics) , engineering , coating
Moisture‐resistant and mechanically strong polyimide (PI)‐polymethylsilsesquioxane hybrid aerogels with doubly cross‐linked structures are synthesized through sol–gel technology and supercritical CO 2 fluid drying. By using bis(trimethoxysilylpropyl) amine as a cross‐linker, the end‐capped polyamide acid derived from biphenyl‐3,3′,4,4′‐tetracarboxylic dianhydride and 4,4′‐oxydianiline is cross‐linked with a silica network using methyltrimethoxysilane as the silica source precursor. The resultant hybrid aerogels show low density (0.12–0.15 g cm −3 ), low thermal conductivity (0.032–0.049 W m −1 K −1 ), high hydrophobicity (125–140°) and good thermal stability (above 435 °C) with tunable microstructure. With the increase of silica sol volume, the microstructure of hybrid aerogels transforms from fibrous network to hierarchical microstructure. Aerogels with high content of silica sol exhibit good moisture resistance, high Young's modulus (Max. 19.6 MPa), and high specific modulus (Max. 131 kN m kg −1 ), which are attributed to their unique hierarchical microstructure with a sheet skeleton. These hybrid aerogels are promising in the fields of thermal insulation, aerospace applications and so on.