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Polymerization of Substituted Acetylenes Using Well‐Defined Rhodium Complex Catalyst. Chirality Transfer and Amplification in Chiral‐Chiral Block and Random Copolymers
Author(s) -
Goto Masahide,
Nito Ayaka,
Miyagi Yu,
Sanda Fumio
Publication year - 2019
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201970021
Subject(s) - copolymer , chirality (physics) , phenylacetylene , materials science , rhodium , polymerization , polymer chemistry , monomer , catalysis , organic chemistry , chemistry , polymer , composite material , physics , chiral symmetry , quantum mechanics , nambu–jona lasinio model , quark
Inside Front Cover : In article number 1900275, Fumio Sanda and coworkers synthesize block and random copolymers by the polymerization of l ‐ and d ‐valine‐derived phenylacetylene monomers using a well‐defined rhodium complex catalyst. The authors demonstrate the chirality transfer and amplification in the block and random copolymers, respectively. The transmitted chirality of the block copolymers is kept memorized upon changing temperature.