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An Efficient Post‐Polymerization Modification of Poly(Styrene‐ co ‐Maleic Anhydride) for Thermally Reversible Nanocomposites
Author(s) -
PavíaSanders Adriana,
Nissen April,
O'Bryan Greg
Publication year - 2018
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201800278
Subject(s) - materials science , maleic anhydride , nanocomposite , copolymer , styrene , polymer chemistry , polymerization , polymer , chemical engineering , composite material , engineering
Abstract A copolymer of maleic anhydride and styrene is functionalized with Diels–Alder (DA) capable pendant groups to enable the study of this material with different crosslink densities. This constituent is synthesized using commercially available starting materials and relatively simple and uncomplicated chemistries which open the possibility for its use in large‐scale applications. The 10%, 25%, 50%, and 100% DA nominal crosslinking based on available pendant furan groups on the polymeric component is investigated. The reaction kinetics are monitored using infrared spectroscopy and rheology. Based on the rheological results, carbon nanotube (CNT) incorporation into the DA matrix is explored in order to determine its effects on the complex modulus of the material. This work is meant as a proof of concept for this DA material with the possibility of its incorporation into other commonly used bulk materials and/or adhesives to allow for an easily reversible product formulation.