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A PSS‐Free PEDOT Conductive Film Supported by a Hierarchical Nanoporous Layer Glass
Author(s) -
Fujima Takuya,
Uchiyama Kentaro,
Yasumoro Keita,
Ito Takumi,
Tabata Erika
Publication year - 2018
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201800183
Subject(s) - materials science , pedot:pss , nanoporous , electrical conductor , indium tin oxide , conductive polymer , formability , composite material , layer (electronics) , transparent conducting film , conductivity , substrate (aquarium) , polyethylene naphthalate , polymer , nanotechnology , chemistry , oceanography , geology
The importance of transparent conductive film is increasing due to its use in applications such as touch‐panel devices. Although indium tin oxide is widely used because of its high conductivity and transparency, conductive polymers are being studied as alternative materials that avoid the use of rare metals and the brittleness associated with existing systems. Polyethylene dioxythiophene (PEDOT)/polyethylene sulfonic acid (PSS) is drawing a lot of attention due to its well‐balanced conductivity, transparency, film formability, and chemical stability. The nonconductive PSS reportedly covers the conductive PEDOT. The PSS shell provides carrier and film‐formability to PEDOT but is also a barrier that hinders electrical conductivity. Therefore, the PEDOT film formability is explored supported by a substrate without the addition of PSS. The “hierarchical nanoporous layer glass” holds the PSS‐free PEDOT with its nanopores to form a homogeneous, transparent film. The PSS‐free PEDOT film thus achieves transparency of over 85% and resistivity of below 500 Ω sq −1 .