Premium
Nanostructured Biopolymer/Few‐Layer Graphene Freestanding Films with Enhanced Mechanical and Electrical Properties
Author(s) -
Silva Cláudia,
Caridade Sofia G.,
Cunha Eunice,
Sousa Maria P.,
Rocha Helena,
Mano João F.,
Paiva Maria C.,
Alves Natália M.
Publication year - 2018
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201700316
Subject(s) - materials science , graphene , exfoliation joint , layer by layer , ultimate tensile strength , composite material , layer (electronics) , graphene oxide paper , graphite , biopolymer , nanotechnology , polymer
In the present work, novel freestanding multilayered films based on chitosan (CHI), alginate (ALG), and functionalized few‐layer graphene are developed through layer‐by‐layer assembly. First, functionalized few‐layer graphene aqueous suspensions are prepared from graphite by a stabilizer‐assisted liquid phase exfoliation process, using a pyrene derivative as stabilizer. Afterward, the films are produced and their physical, morphological, thermal, and mechanical properties are evaluated. Furthermore, their degradation and swelling profiles, as well as their biological behavior, are assessed. The incorporation of functionalized few‐layer graphene results in films with a nanolayered structure, lower roughness than the control CHI/ALG films, and hydrophilic behavior. The mechanical characterization reveals an increase of the Young's modulus, ultimate tensile strength, and elongation at break due to the incorporation of the graphene derivative. A decrease in the electrical resistivity of the multilayered films is also observed. The biological assays reveal improved cytocompatibility toward L929 cells when functionalized few‐layer graphene is incorporated in the CHI/ALG matrix. Therefore, these new graphene‐reinforced multilayered films exhibit interesting properties and great potential for biomedical applications, particularly in wound healing and cardiac and bone tissue engineering.