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Light‐Induced Bulk Architecturation of PDMS Membranes
Author(s) -
Stricher Arthur,
Rinaldi Renaud G.,
Machado Guilherme,
Chag Gregory,
Favier Denis,
Chazeau Laurent,
Ganachaud François
Publication year - 2016
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201600237
Subject(s) - materials science , elastomer , membrane , biocompatible material , silicone , biomaterial , anisotropy , curing (chemistry) , nanotechnology , composite material , biomedical engineering , optics , chemistry , engineering , physics , biochemistry
One major challenge of biomaterial engineering is to mimic the mechanical properties of anisotropic, multifunctional natural soft tissues. Existing solutions toward controlled anisotropy include the use of oriented reinforcing fillers, with complicated interface issues, or UV‐curing processing through patterned masks, that makes use of harmful photosensitive molecules. Here, a versatile process to manufacture biocompatible silicone elastomer membranes by light degradation of the platinum catalyst prior to thermal cross‐linking is presented. The spatial control of network density is demonstrated by experimental and theoretical characterizations of the mechanical responses of patterned cross‐linked membranes, with a view to mimic advanced implantable materials.