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Mechano‐Morphological Characterization of Polyethylene‐Glycol Based Polyurethane Microgel
Author(s) -
Arzumand Ayesha,
Srinivas Shruti,
Yuan Yuan,
Zhou Chi,
Sarkar Debanjan
Publication year - 2016
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201600186
Subject(s) - materials science , colloid , rheology , polyethylene glycol , chemical engineering , polymer , colloidal silica , morphology (biology) , polyurethane , polymer chemistry , composite material , engineering , genetics , biology , coating
Segmental polyurethanes (PU) with hydrophilic segments form colloidal dispersions which are ultimately arrested into gel‐like structure in aqueous continuous phase owing to the differential interactions between polymer and solvent. These structural states of amphiphilic PUs evolve hierarchically, but the structure‐function correlation between PU colloidal dispersion and gels is not clear. Here, this correlation is defined from the mechanomorphology of hydrophilic polyethylene glycol based PU which forms dispersions and finally transforms into gel‐structure. Morphological and rheological analyses show that PU with comparable hydrophilic and hydrophobic content forms attractive colloids with self‐similar fractal microstructures whereas PU with increased hydrophilic character forms space‐filling colloids without any defined organization. Furthermore, colloidal dispersions are densified under shear or gravity to form gel where gel mechanics is defined by colloidal particle organization and the morphology is dependent on gelation mode. This stepwise organization of PU colloidal particles into microgel can independently control microgel mechanics and morphology.