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Isothermal Crystallization Kinetics of Poly (Ethylene 2,5‐Furandicarboxylate)
Author(s) -
van Berkel Jesper G.,
Guigo Nathanaël,
Kolstad Jeffrey J.,
Sipos Laszlo,
Wang Bing,
Dam Matheus A.,
Sbirrazzuoli Nicolas
Publication year - 2015
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201400376
Subject(s) - crystallization , activation energy , materials science , kinetics , polyester , ethylene , ethylene glycol , enthalpy , diffusion , polymer chemistry , chemical engineering , isothermal process , amorphous solid , catalysis , thermodynamics , chemistry , crystallography , organic chemistry , composite material , physics , quantum mechanics , engineering
Poly(ethylene 2,5‐furandicarboxylate) (PEF) is a polyester from ethylene glycol and 2,5‐Furandicarboxylic acid which has gained increasing interest due to its excellent properties compared to chemically similar PET. This paper presents an estimation of the crystallization enthalpy, the crystalline and amorphous density and the crystallization kinetics of PEF. Using Avrami and the Hoffman‐Lauritzen theory, Hoffman‐Lauritzen parameters are proposed that relate crystal growth rate of catalyst‐free PEF to temperature and molecular weight. Characteristic is a higher activation energy for chain diffusion (U*) for PEF compared PET, which can be attributed to more restricted chain conformational changes. Finally, the crystallization rate of PEF is shown to be significantly affected by catalyst type.