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Gas‐Pressure Molding‐Based Fabrication of Smart Actuators from Nematic Liquid‐Crystalline Elastomer
Author(s) -
Torras Núria,
Marshall Jean E.,
Zinoviev Kirill E.,
Camargo Carlos J.,
Terentjev Eugene M.,
Esteve Jaume
Publication year - 2014
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201300462
Subject(s) - materials science , actuator , elastomer , fabrication , liquid crystal , finite element method , molding (decorative) , carbon nanotube , smart material , composite material , optoelectronics , nanotechnology , structural engineering , computer science , medicine , alternative medicine , pathology , artificial intelligence , engineering
A nematic liquid‐crystalline elastomer enriched with carbon nanotubes (LCE‐CNT) is used to obtain an array of photosensitive actuators based on siloxane chemistry. By the combination of a molding technique together with the application of a controlled gas‐pressure during the crosslinking process, it is possible to obtain well‐aligned arrays of monodomain regions within a polydomain in a single step, creating rounded‐shaped features. Localized optical actuation is demonstrated producing measured changes in height up to 120 μm under illumination, which represent a contraction of about 13% of the features. Finite element modeling was used to tune the experimental conditions – pressure loading – according the size of the actuators, maximizing the vertical displacement reached under illumination. This scalable method overcomes previously reported techniques, broadening technological resources development of novel and customized optically driven actuators and devices.