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Nanocomposite Membranes for Polymer Electrolyte Fuel Cells
Author(s) -
Krishnan Nagappan Nambi,
Henkensmeier Dirk,
Jang Jong Hyun,
Kim HyoungJuhn
Publication year - 2014
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201300378
Subject(s) - materials science , membrane , boron nitride , electrolyte , nanocomposite , polymer , nanoparticle , conductivity , chemical engineering , metal , polymer nanocomposite , conductive polymer , nanotechnology , composite material , metallurgy , electrode , chemistry , engineering , biochemistry
Nanoparticles are known to play several roles as polymer fillers, among them reducing the bulk material price or adjusting the mechanical properties. In ion conducting polymer membranes, nanoparticles are also used to manipulate the water balance and fuel permeability of the membrane and to increase the ion conductivity. Suitable materials are metal oxides (SiO 2 , TiO 2 , etc.), electron deficient boron nitride or ion conductive functionalized metal oxides (SZrO 2 , HPASiO 2 , etc.). This article shows which membrane properties can be addressed by adding nanoparticles and describes the underlying mechanisms.