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Biodegradable Bicomponent Fibers from Renewable Sources: Melt‐Spinning of Poly(lactic acid) and Poly[(3‐hydroxybutyrate) ‐co‐ (3‐hydroxyvalerate)]
Author(s) -
Hufenus Rudolf,
Reifler Felix A.,
ManiuraWeber Katharina,
Spierings Adriaan,
Zinn Manfred
Publication year - 2012
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.201100063
Subject(s) - biocompatibility , materials science , ultimate tensile strength , lactic acid , crystallization , composite material , melt spinning , biodegradation , spinning , polyester , modulus , chemical engineering , bacteria , organic chemistry , chemistry , biology , engineering , metallurgy , genetics
PHBV is produced by bacteria as intracellular carbon storage. It is advantageous concerning biocompatibility and biodegradability, but its low crystallization rate hinders the melt‐processing of fibers. This problem can be overcome by combining PHBV with PLA in a core/sheath configuration and introducing a new spin pack concept. The resulting PHBV/PLA bicomponent fibers show an ultimate tensile stress of up to 0.34 GPa and an E‐modulus of up to 7.1 GPa. XRD reveals that PLA alone is responsible for tensile strength. In vitro biocompatibility studies with human fibroblasts reveal good cytocompatibility, making these fibers promising candidates for medical therapeutic approaches.