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Preparation of cis ‐1,4‐Polyisoprene Electrospun Microfibers
Author(s) -
Hao Xiufeng,
Bai Chenxi,
Huang Yue,
Bi Jifu,
Zhang Chunyu,
Cai Hongguang,
Zhang Xuequan,
Du Liping
Publication year - 2010
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200900284
Subject(s) - materials science , electrospinning , microfiber , chloroform , fourier transform infrared spectroscopy , polymer , composite material , scanning electron microscope , elastomer , polymer chemistry , chemical engineering , organic chemistry , chemistry , engineering
cis ‐1,4‐Polyisoprene, a significant industrial elastomer, is electrospun into different nanostrucutures. Cis ‐1,4‐polyisoprene electrospun fibers are prepared from cis ‐1,4‐polyisoprene solutions in dichloromethane or chloroform and characterized by environmental scanning electron microscope and Fourier‐transform infrared spectroscopy. ESEM observation reveals that the cis ‐1,4‐polyisoprene fibers show a bamboo‐like morphology with a nearly constant node distance, a diameter of 20–60 µm and a length of about 300 µm. In addition, within the individual nodes parallel grooves are clearly seen, which is very promising for their use in microprinting in the field of microelectronics. Smooth cis ‐1,4‐polyisoprene fibers with a diameter of 5–8 µm can be obtained via electrospinning its chloroform solutions. In contrast to most polymers, the jet of cis ‐1,4‐polyisoprene does not split during the electrospinning processes, which facilitates the collection of highly aligned fibers by using a rotating mandrel as a ground target.