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Stiffening of Polycarbonate by Addition of a Highly Dispersed and Fibrillated Amorphous Polyamide‐Based Nanocomposite
Author(s) -
Goitisolo Izaro,
Eguiazábal José Ignacio,
Nazabal Jon
Publication year - 2010
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200900263
Subject(s) - materials science , nanocomposite , organoclay , polyamide , compatibilization , composite material , polycarbonate , dynamic mechanical analysis , amorphous solid , montmorillonite , polymer , polymer blend , copolymer , organic chemistry , chemistry
Ternary systems consisting of blends of polycarbonate (PC) from bisphenol A and minority amounts of an amorphous polyamide reinforced with organically modified nanoclay (naPA), were obtained in the melt state. The nanoclay was widely exfoliated inside the dispersed naPA phase. The dispersed phase exhibited a very fine size (up to 0.36 µm), indicating compatibilization. Compatibilization was attributed to interactions between the aPA and the PC. The nanocomposite showed a lower compatibility than their corresponding blends. This lower compatibility of the nanocomposite was attributed to a hindrance of the interaction by the migrated surfactant of the organoclay. The presence of fibrillation in conjunction with a dispersed nanoclay resulted in additive enhancing effects on the modulus and yield stress. This led to modulus increases up to 46% with respect to that of the neat matrix upon the addition of 25% naPA‐10. Besides exhibiting these remarkable modulus values, these systems show an elongation at break similar to that of the neat PC matrix.