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Fiberboards Based on Sugarcane Bagasse Lignin and Fibers
Author(s) -
Hoareau William,
Oliveira Francielli B.,
Grelier Stephane,
Siegmund Bernard,
Frollini Elisabete,
Castellan Alain
Publication year - 2006
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200600004
Subject(s) - bagasse , organosolv , lignin , furfuryl alcohol , fiberboard , materials science , steam explosion , phenol , formaldehyde , phenol formaldehyde resin , raw material , pulp and paper industry , adhesive , curing (chemistry) , organic chemistry , composite material , chemistry , catalysis , layer (electronics) , engineering
Summary: Fiberboards were prepared using phenolic type resins (phenol‐formaldehyde) and sugarcane bagasse fibers. Lignin extracted through an organosolv process from sugarcane bagasse was used as substitute of phenol in phenolic resins from 40 (lignin‐phenol‐formaldehyde) to 100 wt.‐% (lignin‐formaldehyde) substitution. Some of the fibers were chemically modified by oxidation with chlorine dioxide and treatment with furfuryl alcohol (FA), leading to fibers coated with polyfurfuryl alcohol. Thermal analysis (DSC and TGA) of the prepolymers allowed setting up an efficient curing to prepare fiberboards. Impact strength and water absorption were measured showing the importance of the curing pressure to obtain good performance. When chemically modified fibers were used to prepare board samples, enhanced durability against white root fungi is observed, and to a less degree against brown root fungi. Sugarcane bagasse fiberboards were prepared from prepolymers where lignin substituted phenol up to 100%. This replaces these materials in advantageous position, relating to those prepared from phenol‐formaldehyde resins, due to their high content of renewable raw materials. The results obtained are promising for the utilization of sugarcane bagasse as raw materials for preparing fiberboards to be used in tropical areas.Stabilization of sugarcane bagasse fiberboards made with unmodified and modified (ClO 2 + furfuryl alcohol) fibers and phenolic resin after 8 weeks exposure against fungi.