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Preparation of Poly(ethylene terephthalate)/Poly(amino ether) Blends by means of the Addition of Poly(butylene terephthalate)
Author(s) -
Granado Ainhoa,
Eguiazábal José I.,
Nazábal Jon
Publication year - 2004
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200400119
Subject(s) - materials science , composite material , ethylene , ether , dynamic mechanical analysis , polymer blend , modulus , ductility (earth science) , poly ethylene , young's modulus , polymer chemistry , polymer , copolymer , organic chemistry , creep , chemistry , catalysis
Abstract Summary: Blends based on poly(ethylene terephthalate), PET, with poly(amino ether) (PAE) contents up to 40% were obtained by the addition of 20% poly(butylene terephthalate) (PBT) to the PET matrix. PBT mixed with PET led to a decrease in the T m of the matrix that was enough to produce homogeneous blends by mixing in the melt state. Despite the presence of a single peak observed by dynamic‐mechanical analysis, the blends were biphasic, with amorphous phases in which minor amounts of the other component, both reacted and mixed, were present. This presence of minor components gave a fine morphology and significant adhesion that, together with the higher orientation of PAE in the blends, produced blends with a clear synergism in the modulus of elasticity, notched impact strength similar to that of the neat components, and high ductility up to 30% PAE.Young's modulus of the PET‐PBT/PAE blends.