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Effects of Temperature and Surfactants on the Equilibrium Swelling Behavior of Poly[acrylamide‐ co ‐(itaconic acid)] Hydrogels
Author(s) -
Çaykara Tuncer,
Doğmuş Melike
Publication year - 2004
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200400037
Subject(s) - self healing hydrogels , swelling , itaconic acid , acrylamide , polymer chemistry , aqueous solution , cationic polymerization , materials science , chemical engineering , polymer , chemistry , organic chemistry , monomer , composite material , engineering
Summary: The swelling equilibrium of poly(acrylamide) [PAAm] and poly[acrylamide‐ co ‐(itaconic acid)] [P(AAm/IA)] hydrogels was studied as a function of temperature and IA content in aqueous solutions of surfactants: sodium dodecyl sulfate (SDS, anionic) and hexadecyltrimethylammonium bromide (HTAB, cationic). P(AAm/IA) hydrogels in water exhibited reentrant conformational transitions depending on temperature, whereas PAAm hydrogels were not affected with the change of temperature. The equilibrium‐volume‐swelling ratio of P(AAm/IA) hydrogels increased sharply in SDS solutions, with an increase of the mole percent of IA. However, in HTAB solution, the equilibrium‐volume‐swelling ratio of these hydrogels decreased with an increase of IA content.The equilibrium volume‐swelling ratios of the hydrogels in water shown as a function of temperature.