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Fracture Behaviour of Styrene/Butadiene Block Copolymers having Different Molecular Architecture
Author(s) -
Adhikari Rameshwar,
Lach Ralf,
Michler Goerg H.,
Weidisch Roland,
Knoll Konrad
Publication year - 2003
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200390039
Subject(s) - materials science , copolymer , composite material , toughness , charpy impact test , lamellar structure , fracture toughness , brittleness , fracture mechanics , ultimate tensile strength , ductility (earth science) , thermoplastic elastomer , elastomer , tensile testing , polymer , creep
The crack toughness behaviour of styrene/butadiene block copolymers of triblock and star architectures was investigated using instrumented Charpy impact testing. In order to evaluate adequately the toughness behaviour of the investigated materials, different concepts of elastic‐plastic mechanics ( J ‐integral and crack‐tip opening displacement, CTOD concepts) were used. Although the lamellar block copolymers showed a remarkably enhanced ductility in the tensile test than the neat block copolymer having hexagonal PB cylinders in PS matrix, no pronounced difference in crack toughness was found. This behaviour implies that the tensile strain cannot be regarded as the only parameter defining the toughness value. A brittle/tough transition was observed in a lamellar star block copolymer on blending with a linear thermoplastic elastomeric SBS triblock copolymer.SEM micrograph showing the details of the stable crack propagation region in a binary block copolymer blend.