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Simulation of Nylon 6 Polymerization in an Industrial Two‐Step VK Tubular Reactor
Author(s) -
Wenhua Xiao,
Huang Nanxun,
Tang Zhilian,
FilippiniFantoni Roberto
Publication year - 2003
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200390015
Subject(s) - materials science , polymerization , caprolactam , residence time (fluid dynamics) , work (physics) , nylon 6 , thermodynamics , polymer chemistry , polymer , chemical engineering , composite material , physics , geotechnical engineering , engineering
A commonly used nylon 6 two‐step VK tubular reactor is simulated in this work. To verify the reliability of the model, careful comparison with results obtained on different continuous plants is made. The effect of various conditions and parameters, e.g. feed composition, temperature, pressure, etc. on the product properties such as caprolactam conversion, degree of polymerization ( DP ), dimer, integral heat and their distribution index is studied. It is observed that the caprolactam conversion and DP of the product may be affected by various conditions in the first stage and the temperature profile at the top of the second stage, but they finally reach the equilibrium values if the residence time is long enough. The most effective way to increase DP of the product is to increase the vacuum at the top of the second stage.CPL conversion and DP profile for pressure of tube 2: 0.032, 0.037, 0.042 mPa; other parameters as given for example A of Table 5.