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Thermoplastic Elastomers Derived from Scrap Rubber Powder/LLDPE Blend with LLDPE‐ graft ‐(Epoxidized Natural Rubber) Dual Compatibilizer
Author(s) -
Guo Baochun,
Cao Yan,
Jia Demin,
Qiu Qinghua
Publication year - 2004
Publication title -
macromolecular materials and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.913
H-Index - 96
eISSN - 1439-2054
pISSN - 1438-7492
DOI - 10.1002/mame.200300311
Subject(s) - linear low density polyethylene , materials science , natural rubber , composite material , thermoplastic elastomer , thermoplastic , elastomer , vulcanization , polymer blend , polymer , copolymer
Summary: Attempts were made to prepare thermoplastic elastomers (TPE) from scrap rubber powder (SRP) and linear low‐density polyethylene (LLDPE) as thermoplastic polymer matrix. The solid‐phase grafted copolymer of LLDPE (LLDPE‐g‐VM) and epoxidized natural rubber (ENR) were used as dual compatibilizers to improve the interfacial adhesion between SRP and LLDPE. The compatibilized SRP/LLDPE blends had obviously improved the interfacial properties between SRP particles and LLDPE. Using this method, thermoplastic elastomer was prepared successfully. The mechanical properties especially elongation at break was improved significantly. SEM and TEM studies showed that the ENR/LLDPE‐g‐VM dual compatibilizer improved the distribution state of SRP particles in LLDPE and the adhesion between SRP and LLDPE. DSC results showed a distinct glass transition at 74 °C of the interfacial region. The improvement in mechanical properties was attributed to the enhanced interfacial properties of the blend.Surface of SRP particles of the composites compatibilized by the dual compatibilizer.