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Ring Opening Metathesis Polymerization of a New Monomer Derived from a Nitroso Diels–Alder Reaction
Author(s) -
Subnaik Selesha,
Sheridan Katya,
Hobbs Christopher E.
Publication year - 2021
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.202100098
Subject(s) - romp , polymer chemistry , monomer , chemistry , polymerization , ring opening metathesis polymerisation , nitroso compounds , metathesis , polyolefin , cyclopentadiene , nitroso , diels–alder reaction , ring opening polymerization , salt metathesis reaction , organic chemistry , polymer , catalysis , layer (electronics)
A nitroso Diels–Alder (NDA) reaction between cyclopentadiene and an in situ generated nitroso compound leads to a new heterocyclic monomer for ring opening metathesis polymerization (ROMP) reactions. This monomer could be polymerized in the presence of Grubbs‐third generation initiator with good control over M n and decent Ð values. The resulting isoxazolidine‐containing material could undergo further hydrogenation, deprotection, and modification with Dansyl chloride as well as ring opening to provide an amino‐and hydroxyl‐decorated “polyolefin.”