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Halloysite Containing Thermoset Nanocomposites via Free Radical Photocrosslinking Polymerization
Author(s) -
Turp Onur,
Acar Seda Bekin,
Ozdemir Kevser,
Bouharras Fatima Ezzahra,
Raihane Mustapha,
Tasdelen Mehmet Atilla
Publication year - 2020
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.202000197
Subject(s) - thermosetting polymer , halloysite , materials science , nanocomposite , polymer chemistry , radical polymerization , methacrylate , dynamic mechanical analysis , fourier transform infrared spectroscopy , composite material , polymer , polymerization , chemical engineering , engineering
Abstract Naturally occurring halloysite nanotubes (HNTs) are first functionalized by 3‐(trimethoxysilyl) propyl methacrylate and then used as nanofillers in a mixture of difunctional methacrylates (triethylene glycol dimethacrylate and bisphenol A glycerolate dimethacrylate). Upon free radical photocrosslinking of this mixture enables the in situ preparation of HNT/thermoset nanocomposites. The covalent bonding of HNT in the thermoset matrix is proven by following characteristic bands of the mixture using Fourier transformed infrared spectroscopy. Furthermore, the presence and distribution of HNT in the nanocomposites are confirmed by scanning electron microscopy with energy dispersive X‐ray spectroscopy, and transmission electron microscopy observations. In addition, a mixed morphology containing agglomerated/nonagglomerated HNTs in the thermoset matrix is also determined. Both tensile strength and elasticity modulus of nanocomposites are dramatically increased with increase in HNT loading up to 4% ratio. On the other hand, these nanocomposites exhibit higher thermal properties compared to the neat thermoset.