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Multipurpose Degradable Physical Adhesive Based on Poly( d,l ‐lactide‐ co ‐trimethylene Carbonate)
Author(s) -
Fuoco Tiziana,
Almas Ria Afifah,
FinneWistrand Anna
Publication year - 2020
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.202000034
Subject(s) - trimethylene carbonate , adhesive , dispersity , glass transition , materials science , polyester , polymer chemistry , amorphous solid , adhesion , chemical engineering , solvent , surface roughness , ethyl acetate , diffusion , polymer , composite material , chemistry , organic chemistry , copolymer , physics , layer (electronics) , engineering , thermodynamics
Solutions of amorphous poly( d,l ‐lactide‐ co ‐trimethylene carbonate)s (PDLTMCs) in ethyl acetate work as solvent‐based physical adhesives through diffusion mechanisms for a variety of aliphatic polyester‐based adherents. The random PDLTMCs with a trimethylene carbonate content of 11, 16, and 20 mol% are synthesized in bulk, achieving high molecular weight, M n , up to 128 kg mol −1 and dispersity around 1.7. The PDLTMCs are amorphous and have a glass transition temperature in the range 34.7 to 43.6 °C and in agreement with the theoretical values calculated using the Fox equation. The mechanical and surface properties of the PDLTMCs are tested preparing solvent cast films, which are soft and tough and, although they have a higher contact angle than the parent homopolymer, they show higher water uptake capacity. The potential application as adhesives of the synthesized PDLTMCs is evaluated by preparing a 20 wt% solution in ethyl acetate and testing them by adhering films with different compositions as well as constructs having different geometries and surface roughness. The results demonstrate that the adhesion strength is higher on adherent films having similar chemical compositions as the adhesives and on surfaces having similar compositions to each other but different roughness. The similar chemical nature of the adhesive and adherent probably favors the diffusion mechanism through which adhesion takes place.