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Superhydrophobic Porous PLLA Sponges with Hierarchical Micro‐/Nano‐Structures for High‐Efficiency Self‐Cleaning
Author(s) -
Wang Yongtao,
Tian Shilin,
Sun Qingqing,
Liu Wentao,
Duan Ruixia,
Yang Huige,
Liu Xuying,
Chen Jinzhou
Publication year - 2019
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201900338
Subject(s) - crystallinity , porosity , materials science , solubility , solvent , chemical engineering , wetting , biocompatibility , nano , hildebrand solubility parameter , composite material , polymer , chemistry , organic chemistry , engineering , metallurgy
Porous poly ( l ‐lactic acid) (PLLA) sponges have received rapid development in the materials science and energy fields due to their good biocompatibility and degradability. Herein, hierarchical micro‐/nano‐structures of PLLA sponges are successfully prepared by the microphase separation method to investigate the influence of non‐solvents on PLLA microtopography. The interaction ability between PLLA and various alcohol non‐solvents is precisely calculated by using the Flory–Huggins equation. SEM results show that the porosity of PLLA surfaces increases with increasing non‐solvent solubility parameters at a certain range. When the solubility parameters of alcohol non‐solvents are much higher than that of PLLA, PLLA bulks accumulate on the surfaces, mainly caused by its insolubility. DSC curves disclose that the crystallinity has a positive relationship with contents and solubility parameters of alcohol non‐solvents. Furthermore, these porous PLLA surfaces show strong water repellency and self‐cleaning ability so that the contaminant can be quickly cleared away from the PLLA surfaces. This study provides a new insight into understanding the formation process of PLLA porous materials and the wetting variation for high‐efficiency self‐cleaning.