Poly(phosphoester) Colloids by Interfacial Polycondensation in Miniemulsion | Zendy

Alexandrino Evandro M. | Zendy; Wagner Manfred | Zendy; Landfester Katharina | Zendy; Wurm Frederik R. | Zendy

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Poly(phosphoester) Colloids by Interfacial Polycondensation in Miniemulsion

Author(s) -

Alexandrino Evandro M.,

Wagner Manfred,

Landfester Katharina,

Wurm Frederik R.

Publication year - 2016

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.201600218

Subject(s) - miniemulsion , condensation polymer , heteronuclear molecule , polymer chemistry , materials science , colloid , hydrolysis , polyphosphate , chemistry , chemical engineering , polymer , nuclear magnetic resonance spectroscopy , polymerization , organic chemistry , phosphate , engineering

Size matters: the interface of nanodroplets in an inverse miniemulsion is used to produce polyphosphate nanocapsules by interfacial polycondensation. Phosphorus acts as a probe for 31 P NMR spectroscopy to compare the polycondensation at the nanoscopic droplet with macroscopic interfaces proving less unwanted hydrolysis in miniemulsion by 1 H– 31 P 2D‐heteronuclear multiple bond correlation spectra.

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