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Poly(methyl methacrylate)/Graphene Microparticles Having a Core/Shell Structure Prepared with Carboxylated Graphene as a Pickering Stabilizer
Author(s) -
Erdenedelger Gansukh,
Dao Trung Dung,
Jeong Han Mo
Publication year - 2016
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201500349
Subject(s) - methyl methacrylate , composite number , materials science , polymer chemistry , graphene , acrylic acid , stabilizer (aeronautics) , methacrylate , percolation threshold , polymerization , chemical engineering , composite material , copolymer , polymer , electrical resistivity and conductivity , nanotechnology , mechanical engineering , electrical engineering , engineering
Two kinds of carboxylated thermally reduced graphenes (carboxylated TRGs) with different lateral sizes are examined as a Pickering stabilizer in the suspension polymerization of methyl methacrylate. The size and the shape of the prepared composite particles are irregular due to agglomeration, more evidently when the larger carboxylated TRG is used. In addition, carboxylated TRG is distributed not only on the surface but also inside the composite particles. It indicates that the carboxylated TRG alone is not a stable Pickering agent. However, a very small dosage of acrylic acid remedies all these issues because acrylic acid interacts with carboxylated TRG and synergizes the stabilizing effect. The compression molded composite of the core/shell poly(methyl methacrylate)/carboxylated TRG particles exhibits a very low percolation threshold of electrical conductivity of 0.03 vol%. It demonstrates that the carboxylated TRG shells of the composite particles effectively form a segregated conductive network throughout the composite.