Vanadyl‐TrBR 4 ‐Catalyzed Oxidative Polymerization of Diphenyl Disulfide | Zendy

Aida Fuyuki | Zendy; Yamaguchi Souske | Zendy; Takatori Yohei | Zendy; Nagamatsu Kentaro | Zendy; Kiyokawa Daichi | Zendy; Oyaizu Kenichi | Zendy; Nishide Hiroyuki | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Vanadyl‐TrBR 4 ‐Catalyzed Oxidative Polymerization of Diphenyl Disulfide

Author(s) -

Aida Fuyuki,

Yamaguchi Souske,

Takatori Yohei,

Nagamatsu Kentaro,

Kiyokawa Daichi,

Oyaizu Kenichi,

Nishide Hiroyuki

Publication year - 2015

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.201500154

Subject(s) - polymerization , chemistry , polymer chemistry , monomer , catalysis , sulfide , polymer , organic chemistry

A newly established catalyst system for oxygen‐oxidative polymerization of diphenyl disulfide is reported. Combination of vanadyl compounds (e.g., VO(acac) 2 ) and triphenylmethylium tetrakis(pentafluorophenyl)borate (TrB(C 6 F 5 ) 4 ) proceeds the polymerization to give poly(1,4‐phenylene sulfide) (PPS) at 100 °C. When triphenylmethylium tetrafluoroborate (TrBF 4 ) is applied with vanadyl tetraphenylporphyrin (VO(TPP)) or N,N′ ‐(ethylenebis(salicylideneaminato))oxovanadium (VO(salen)), PPS is also given via polymerization under conditions near 160 °C. Combination of the vanadyl complex and the borate affords the first protic‐acid‐free catalytic system for the polymerization of the disulfide, suggesting the overall reaction to produce PPS and H 2 O from O 2 and protons that are eliminated from the monomer.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research