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Polymer Interphase Self‐Reinforcement and Strengthening Mechanisms in Low‐Loaded Nanocomposite Fibers
Author(s) -
Song Kenan,
Zhang Yiying,
Minus Marilyn L.
Publication year - 2015
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201500011
Subject(s) - composite material , interphase , materials science , polyvinyl alcohol , ultimate tensile strength , nanocomposite , composite number , polymer , stacking , modulus , polymer nanocomposite , amorphous solid , chemistry , crystallography , genetics , organic chemistry , biology
The effect of filler concentration on understanding structure–property relationships in polymer composites with low nanocarbon (nC) loadings (<1 wt%) is investigated. The presence of the carbon nanochips (CNC) filler induces the formation of highly ordered self‐reinforcing interphase regions within the composite fibers. The influence of these regions on the structure and properties of the fibers is analyzed by both theoretical and experimental methods. Analysis of the filled polyvinyl alcohol (PVA) fibers demonstrates that the presence of the nC influences the organization and formation of crystalline and amorphous polymer lamellae stacking in the fibers, leading to variations in grain structure for the composites. These structural developments contribute specifically to the property increases (i.e., elastic modulus increased by 222% and tensile strength increased by 186%) for the PVA/CNC composites in comparison to control PVA fibers.