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Effects of Isophorone Diisocyanate on the Thermal and Mechanical Properties of Shape‐Memory Polyurethane Foams
Author(s) -
Hasan Sayyeda M.,
Raymond Jeffery E.,
Wilson Thomas S.,
Keller Brandis K.,
Maitland Duncan J.
Publication year - 2014
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201400407
Subject(s) - isophorone diisocyanate , polyurethane , materials science , isophorone , glass transition , polymer , plasticizer , composite material , shape memory polymer , aqueous solution , chemical engineering , polymer chemistry , chemistry , organic chemistry , diamine , engineering
Previously developed shape‐memory polymer foams display fast actuation in water due to plasticization of the polymer network. The actuation presents itself as a depression in the glass‐transition temperature when moving from dry to aqueous conditions; this effect limits the working time of the foam to 10 min when used in a transcatheter embolic device. Reproducible foams are developed by altering the chemical backbone, which can achieve working times of greater than 20 min. This is accomplished by incorporating isophorone diisocyanate into the foam, resulting in increased hydrophobicity, glass transitions, and actuation time. This delayed actuation, when compared with previous systems, allows for more optimal working time in clinical applications.