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Synthesis and 13 C NMR Spectroscopy Analysis of Ethylene Copolymer with High Content of 4‐Penten‐1‐ol
Author(s) -
Wang Wei,
Hou Liping,
Luo Shuiyuan,
Zheng Gang,
Wang Hongtao
Publication year - 2013
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201300350
Subject(s) - copolymer , ethylene , polymer chemistry , catalysis , nuclear magnetic resonance spectroscopy , chemistry , spectroscopy , materials science , organic chemistry , polymer , physics , quantum mechanics
Copolymerization of ethylene with 4‐penten‐1‐ol (4P1O) is conducted by using a half‐titanocene catalyst. The incorporation of 4P1O is high as approximately 10 mol%. The assignments of the 13 C NMR spectrum and the analysis of the sequence distribution show the existence of not only the alternative structure but also the repeated 4P1O units. The product of the reactive ratios is calculated as ca. 2.