Premium
Glycidyl 4‐Functionalized‐1,2,3‐Triazole Polymers
Author(s) -
Liu Dian,
Zheng Yijun,
Steffen Werner,
Wagner Manfred,
Butt HansJürgen,
Ikeda Taichi
Publication year - 2013
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201200563
Subject(s) - polymer chemistry , polymer , cycloaddition , surface modification , ethylene glycol , azide , click chemistry , functional polymers , chemistry , glass transition , triazole , materials science , solubility , polymerization , organic chemistry , catalysis
A series of novel polymers, glycidyl 4‐functionalized 1,2,3‐triazole polymers (functionalized GTP) were synthesized by click functionalization of glycidyl azide polymer (GAP). Quantitative functionalization of the glycidyl polymer side groups was achieved due to the high reactivity of the azide–alkyne Huisgen cycloaddition under mild conditions. The polymers were characterized by 1 H NMR, 13 C NMR, IR, GPC, DLS, DSC, and TGA. We confirmed that the solubility, glass transition temperature, and decomposition temperature were controllable by changing the functional group attached at 4‐position of 1,2,3‐triazole group. Functionalized GTP expands not only the application field of GAP toward non‐explosive materials, but also the variety of poly(ethylene glycol) derivatives with different side groups.