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Nanostructured Films of Block Copolymers Functionalized With Photolabile Protected Amino Groups
Author(s) -
Stadermann Jan,
Riedel Maria,
Voit Brigitte
Publication year - 2013
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201200409
Subject(s) - copolymer , polymer chemistry , raft , reversible addition−fragmentation chain transfer polymerization , polymerization , block (permutation group theory) , materials science , characterization (materials science) , click chemistry , nanostructure , chemistry , chemical engineering , polymer , nanotechnology , organic chemistry , radical polymerization , geometry , mathematics , engineering
Abstract Two phase separating block copolymers with photolabile protected amino groups in one block have been synthesized through RAFT polymerization followed by efficient click modification. Techniques like NMR, GPC, and DSC were applied for the characterization of these functional materials. The block copolymers were used for the preparation of thin films where they assemble to form distinct nanostructures as detected by AFM analysis.