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Novel Glycopolymer Brushes via ATRP: 1. Synthesis and Characterization
Author(s) -
Fleet Reda,
van den Dungen Eric T. A.,
Klumperman Bert
Publication year - 2011
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201100288
Subject(s) - glycopolymer , polymer chemistry , chemistry , size exclusion chromatography , grafting , copolymer , materials science , organic chemistry , polymer , enzyme
The synthesis and characterization of a series of glycopolymer brushes with P(methyl 6‐ O ‐methacryloyl‐α‐ D ‐glucoside) (P(6‐ O ‐MMAGIc)) side chains (SCs) is reported. The formation of well‐defined glycopolymer brushes is confirmed by 1 H NMR spectroscopy and size exclusion chromatography (SEC) with a MALLS detector. Four multifunctional macroinitiators with different topologies and molar masses are prepared. The P(6‐ O ‐MMAGIc) SCs are cleaved from the backbone and analyzed by 1 H NMR and SEC–MALLS, which further confirmed the synthesis of well‐defined glycopolymer brushes. The grafting efficiency of P(6‐ O ‐MMAGIc) from the different macroinitiators are determined to be in the range 0.37 < f < 0.55.