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1,2,3‐Triazole‐Incorporated Diacrylate Monomer for Free Radical Cyclopolymerization Through Large Ring Formation
Author(s) -
Li Changlin,
Liu Hewen,
Li Yuesheng
Publication year - 2011
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201100104
Subject(s) - branching (polymer chemistry) , monomer , polymer chemistry , chemistry , radical polymerization , free radical reaction , radical initiator , ring (chemistry) , dept , radical , polymer , organic chemistry , stereochemistry
A new 1,2,3‐triazole incorporated diacrylate monomer is designed for free radical cyclopolymerization through the formation of 11‐membered rings. NMR analysis on the cyclopolymers including 1 H, 13 C, DEPT‐135, and 1 H– 13 C HMQC spectra support a high degree of cyclization. GPC profiles of the obtained cyclopolymers show unimodal distributions indicative of no chain branching reactions.