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Luminescent Sensory Polymer Coating Composed of Platinumporphyrin and Poly(trimethylsilylpropyne) for Real‐Time Oxygen Visualization in Operating PEFCs
Author(s) -
Hyakutake Tsuyoshi,
Ishigami Yuta,
Kato Junji,
Inukai Junji,
Miyatake Kenji,
Nishide Hiroyuki,
Watanabe Masahiro
Publication year - 2011
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.201000449
Subject(s) - partial pressure , coating , luminescence , pressure sensitive paint , oxygen , polymer , cathode , oxygen sensor , materials science , diffusion , chemical engineering , layer (electronics) , analytical chemistry (journal) , composite material , chemistry , optoelectronics , chromatography , organic chemistry , thermodynamics , physics , wind tunnel , engineering
A luminescent PtTFP/PMSP polymer coating was prepared for the oxygen partial pressure visualization inside a PEFC. PMSP formed a smooth and tough coating as a highly oxygen‐permeable matrix with a thickness of ca. 2 µm in which the PtTFP was homogeneously dispersed. The coating displayed a strong red luminescence with significantly decreasing intensity upon increasing oxygen partial pressure. The sensitivity for the oxygen partial pressure was high and the analytical curve of the sensor polymer coating was undisturbed by external factors. The PtTFP/PMSP sensor was coated on the surface of a cathode gas diffusion layer on the air flow channel inside PEFC. The oxygen‐pressure distribution in the air flow channel was successfully visualized while operating the PEFC.