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Comparative Study of the Solid–Liquid Interface Behavior of Amphiphilic Block and Block‐Like Copolymers
Author(s) -
Bulychev Nikolay,
Van Camp Wim,
Dervaux Bart,
Kirilina Yulia,
Dirnberger Klaus,
Zubov Vitali,
Prez Filip E. Du,
Eisenbach Claus D.
Publication year - 2009
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.200800374
Subject(s) - copolymer , amphiphile , adsorption , block (permutation group theory) , materials science , polymer chemistry , polymer , acrylate , chemical engineering , acrylic acid , chemistry , organic chemistry , composite material , geometry , mathematics , engineering
Amphiphilic block and “block‐like” copolymers based on poly(isobornyl acrylate) and poly(acrylic acid) were used as stabilizers for hydrophilic (titanium dioxide) and hydrophobic (copper phthalocyanine) pigments. As reflected by the dispersion stabilities and electrokinetic sonic amplitude (ESA) measurements, the molecular architecture of the copolymer is of great importance for its interaction with the pigment surface. It was observed that irrespective of polymer composition, block‐like copolymers exhibit lower stabilization ability and quite different adsorption behavior in comparison to block copolymers with sharp block boundaries. Models for the adsorption behavior of both block and block‐like copolymers are proposed.