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Multifunctional Polymethacrylates Obtained Via ATRP of Functional and Reactive Monomers Followed by Polymer Analogous Reaction with Functional Amines
Author(s) -
Popescu Dragos,
Keul Helmut,
Moeller Martin
Publication year - 2008
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.200800213
Subject(s) - methacrylate , monomer , polymer chemistry , copolymer , methyl methacrylate , polymer , chemistry , functional polymers , materials science , organic chemistry
Starting from methyl methacrylate (MMA), butyl methacrylate (BMA), allyl methacrylate (AMA), phenoxycarbonyloxy ethyl methacrylate (PCEMA), and functional amines different multifunctional polymethacrylates are accessible. The reactive monomer PCEMA was synthesized starting from 2‐hydroxyethyl methacrylate, and then copolymerized via ATRP with other methacrylates in order to obtain reactive copolymers which were subjected to polymer analogous reactions with different functional amines leading to multifunctional polymethacrylates. These can be used for the preparation of multifunctional surfaces.