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Synthesis, Characterization, and Photopolymerization of Novel Phosphonated Resins, 2
Author(s) -
Senhaji Omar,
Monge Sophie,
Chougrani Kamel,
Robin JeanJacques
Publication year - 2008
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.200800103
Subject(s) - photopolymer , phosphonate , polymer chemistry , chemistry , polymer , allyl alcohol , acrylate polymer , organic chemistry , polymerization , monomer , catalysis , acrylate
New phosphonated cross‐linked polymers were synthesized from telomers obtained by reaction between 10‐undecenol and dialkyl hydrogenphosphonates. Telomers were studied using MALDI‐TOF MS. It was proven that side products were produced, corresponding to cross‐esterification reactions of dialkyl hydrogenphosphonate on telomers and to radical additions of telomer on 10‐undecenol. The same behavior was also observed with allyl alcohol. Telomers were then converted to resins by methacrylation reactions. Finally, photopolymerization of the different resins synthesized was achieved and influence of the nature of the phosphonate group (diester, monoacid and diacid) was also evaluated.