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Efficient Donor for Terbium Luminescence Based on Polymer Ligand Containing Quinolinone Fluorophore
Author(s) -
Výprachtický Drahomír,
Cimrová Věra,
Kukla Stanislav,
Pavlačková Petra
Publication year - 2006
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.200500454
Subject(s) - chemistry , ligand (biochemistry) , luminescence , fluorophore , acceptor , terbium , methanol , fluorescence , photochemistry , medicinal chemistry , polymer chemistry , organic chemistry , materials science , ion , biochemistry , receptor , physics , optoelectronics , quantum mechanics , condensed matter physics
Summary: Polymer ligand containing a quinolinone fluorophore and carboxyl binding sites ( III ) was synthesized by the reaction of parent poly[styrene‐ alt ‐(maleic anhydride)] with 7‐amino‐4‐methylquinolin‐2(1 H )‐one ( I ) and methanol. The ligand‐to‐metal resonance energy transfer and ligand binding properties of Tb( III )‐ III complexes were investigated by steady‐state and time‐resolved luminescence spectroscopy in methanol or deuterated methanol and compared with those of the low‐molecular‐weight model compound, N ‐[4‐methyl‐2‐oxo‐1,2‐dihydroquinolin‐7‐yl]succinamic acid ( II ). The long‐lived emission intensity of Tb 3+ at 490, 545, 585, and 620 nm corresponding to the 5 D 4 → 7 F 6 , 5 D 4 → 7 F 5 , 5 D 4 → 7 F 4 , and 5 D 4 → 7 F 3 transitions, respectively, was strongly increased by the addition of III (as much as 10 000 times) and decreased in the order of Tb( III )‐ III ≫ Tb( III )‐ II > Tb( III )‐ I > Tb( III ). The efficiency of energy transfer ( E ) was evaluated from emission intensity of the donor ( III) in the presence or absence of the acceptor (Tb 3+ ) as E = 0.71–0.94, depending on the acceptor concentration and ligand neutralization. The experimental luminescence‐decay curves were double‐exponential ( τ 1 , τ 2 ) with a predominating longer component (rel B 1 = 85%) for Tb( III )‐ III and single‐exponential ( τ ) for Tb( III )‐ II . One or three methanol molecules were coordinated to Tb 3+ in Tb( III )‐ III with or without neutralization of III , respectively, whereas approximately 6.5 methanol molecules were coordinated to Tb 3+ in Tb( III )‐ II . Terbium ion coordinates with 7–8 molecules of methanol in methanolic solution.Schematic energy‐level diagram for fluorescence resonance energy transfer in a Tb( III )‐ligand complex.