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Synthesis and Characterization of Segmented Poly(ether ester)s Containing H‐Bonding Units
Author(s) -
Signori Francesca,
Solaro Roberto,
Chiellini Emo,
Lips Priscilla A. M.,
Dijkstra Pieter J.,
Feijen Jan
Publication year - 2003
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.200350057
Subject(s) - monomer , polymer chemistry , copolymer , amide , condensation polymer , differential scanning calorimetry , ether , solubility , chemistry , materials science , organic chemistry , polymer , physics , thermodynamics
A series of poly(ether ester)s containing different H‐bonding units (amide, carbamate, urea) was prepared by polycondensation in bulk, using Ti(OBu) 4 as a catalyst. The copolymers were obtained starting from PEG1000, 1,4‐butanediol, and a symmetrical, bis‐ester terminated monomer carrying H‐bonding units. These materials were designed for biomedical applications, in which ultimate biodegradability of the materials is required. The influence of the nature of the H‐bonding unit and of the length of the methylene spacer between H‐bonding groups on the thermal and solubility properties of copolymers was investigated. Amide containing copolymers were more thermally stable than ones containing carbamate, consistent with the observed behavior of the corresponding monomers. In most cases, differential scanning calorimetry (DSC) traces were quite complex because of phase separation and dependent on the applied cooling rate. Copolymers containing urea bonds were less soluble in most organic solvents, but their thermal properties were not significantly different than their amide containing counterparts.Synthesis of amide‐based diester monomers.