Novel Polymerization of Fluorinated 2‐Vinylcyclopropane in Aqueous Solution via Cyclodextrin Complexes | Zendy

Choi Soo Whan | Zendy; Kretschmann Oliver | Zendy; Ritter Helmut | Zendy; Ragnoli Marina | Zendy; Galli Giancarlo | Zendy

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Novel Polymerization of Fluorinated 2‐Vinylcyclopropane in Aqueous Solution via Cyclodextrin Complexes

Author(s) -

Choi Soo Whan,

Kretschmann Oliver,

Ritter Helmut,

Ragnoli Marina,

Galli Giancarlo

Publication year - 2003

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.200350010

Subject(s) - polymerization , polymer chemistry , chemistry , aqueous solution , copolymer , cyclodextrin , polymer , anionic addition polymerization , ionic polymerization , radical polymerization , organic chemistry

We report on the first examples of the free radical polymerization of a fluorinated 2‐vinylcyclopropane 1 and its copolymerization with an alkyl 2‐vinylcyclopropane 2 in aqueous solution via their host‐guest complexation with a random methylated β ‐cyclodextrin (RAMEB) using a water‐soluble initiator (VA50). Upon polymerization, the dethreaded cyclodextrin remained in water solution, whereas the water‐insoluble polymer precipitated out and was isolated. The polymers prepared exhibited mesophase behavior over a wide range of temperature. Both T g and T i of the copolymers increased linearly with the amount of fluorinated co‐units.Complexation of fluorinated vinylcyclopropane 1 with RAMEB and polymerization in water solution.

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