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Quantitative Aspects of the Dendronization of Dendronized Linear Polystyrenes
Author(s) -
Shu Lijin,
Göossl Illdiko,
Rabe Jürgen P.,
Dieter Schlüter A.
Publication year - 2002
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.200290037
Subject(s) - polymer , molar mass , homologous series , absorbance , polymer chemistry , alkyl , reagent , chemistry , amine gas treating , functional polymers , materials science , copolymer , organic chemistry , chromatography
The paper describes in detail how amine‐terminated dendronized polystyrenes 1 (G2), 2 (G3), and 3 (G1) of varying generations (first: G1, second: G2, third: G3) were reacted with the G1 (and G2) dendrons 4 , 5c , and 6b carrying active esters at their focal point to furnish polymers 7 (G4), 8 (G2), 9 (G3), and 10 (G4). All these dendronization steps were monitored using UV absorbance measurements after labeling the unreacted amines with the Sanger reagent, 2,4‐dinitrofluorobenzene, providing a quantitative assessment of the overall structural integrity achievable for dendronized polymers synthesized according to this divergent growth scheme. Polymers 3 (G1), 8 (G2), 9 (G3), and 10 (G4) represent a quasi‐homologous series of high molar mass dendronized polymers whose lengths and length distributions, in their deprotected (and thus charged) state, was determined by contour‐length histograms using scanning force microscopy (SFM). Finally, the decoration of representatives of this series with long alkyl chains is also reported.