EXAFS study of supported TiCl 4 /MgCl 2  catalyst | Zendy

Potapov Alexandr G. | Zendy; Kriventsov Vladimir V. | Zendy; Kochubey Dmitrii I. | Zendy; Bukatov Gennadii D. | Zendy; Zakharov Vladimir A. | Zendy

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EXAFS study of supported TiCl 4 /MgCl 2 catalyst

Author(s) -

Potapov Alexandr G.,

Kriventsov Vladimir V.,

Kochubey Dmitrii I.,

Bukatov Gennadii D.,

Zakharov Vladimir A.

Publication year - 1997

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.1997.021981112

Subject(s) - extended x ray absorption fine structure , catalysis , chemistry , absorption (acoustics) , adsorption , polymer chemistry , crystallography , materials science , absorption spectroscopy , organic chemistry , optics , physics , composite material

Extended X‐ray absorption fine structure analysis (EXAFS) has been used to study supported TiCl 4 /MgCl 2 catalysts containing 1.8 wt.‐% Ti. Adsorbed TiCl 4 was found to exist on the MgCl 2 surface as a dimeric complex. The possible structures of dimeric TiCl 4 complexes on the (100) face of MgCl 2 are discussed.

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