Synthesis and characterization of poly[3‐(6‐tetra‐hydropyran‐2‐yloxyhexyl)‐2,5‐thienylene] | Zendy

Bolognesi Alberto | Zendy; Mendichi Raniero | Zendy; Schieroni Alberto | Zendy; Villa Daniela | Zendy; Ahumada Oscar | Zendy

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Synthesis and characterization of poly[3‐(6‐tetra‐hydropyran‐2‐yloxyhexyl)‐2,5‐thienylene]

Author(s) -

Bolognesi Alberto,

Mendichi Raniero,

Schieroni Alberto,

Villa Daniela,

Ahumada Oscar

Publication year - 1997

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.1997.021981024

Subject(s) - polymer chemistry , tetra , tetrahydropyran , polymer , fourier transform infrared spectroscopy , catalysis , chemistry , characterization (materials science) , materials science , organic chemistry , chemical engineering , ring (chemistry) , medicinal chemistry , nanotechnology , engineering

The synthesis of poly[3‐(6‐tetrahydropyran‐2‐yloxyhexyl)‐2,5‐thienylene] has been performed with a nickel catalyst, obtaining a highly regioregular polymer. The deprotection of the pyranyl function restores the OH group giving a polymer which is not soluble in the usual organic solvents but soluble in 1‐methyl‐2‐pyrrolidone, indicating that no crosslinks are present. The protected form was characterised by means of GPC, 1 H NMR, FTIR and UV‐Vis spectroscopy and was found to give Langmuir‐Blodgett multilayered structures.

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