Synthesis and radical polymerization behavior of a novel methacrylate with an  L ‐leucyl‐ L ‐alanylglycine peptide moiety | Zendy

Murata Hironobu | Zendy; Sanda Fumio | Zendy; Endo Takeshi | Zendy

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Synthesis and radical polymerization behavior of a novel methacrylate with an L ‐leucyl‐ L ‐alanylglycine peptide moiety

Author(s) -

Murata Hironobu,

Sanda Fumio,

Endo Takeshi

Publication year - 1997

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.1997.021980813

Subject(s) - moiety , polymer chemistry , methacrylate , polymerization , peptide , chemistry , radical polymerization , polymer , organic chemistry , biochemistry

The synthesis and radical polymerization behavior of a novel methacrylate having a peptide moiety, N ‐benzyloxycarbonyl‐ L ‐leucyl‐ L ‐alanylglycine 2‐methacryloyloxyethyl ester ( 1 ), are described. 1 shows radical polymerizability in spite of the bulky peptide moiety. Only the ester group near the peptide moiety of poly( 1 ) could be hydrolyzed selectively and completely in the hydrolysis of poly( 1 ) in an alkaline solution.

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