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Polyhalide derivatives of poly[ N ‐(2‐aminoethyl)‐acrylamido]triethylammonium resins as iodinating reagents
Author(s) -
Mitra Sudha Sumi,
Sreekumar Krishnapillai
Publication year - 1997
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1997.021980523
Subject(s) - reagent , chemistry , selectivity , solvent , halogenation , polymer chemistry , reaction conditions , phenols , organic chemistry , combinatorial chemistry , catalysis
Abstract Poly[ N ‐(2‐aminoethyl)acrylamido]triethylammonium dichloroiodate, tetrachloroiodate and dibromoiodate resins have been developed as a new class of heterogeneous reagents. The use of the polyhalide derivatives for the selective iodination of aromatic amines and phenols is described. The influence of the various reaction parameters including nature of the solvent, effective molar concentration of the reagent and temperature were investigated to find out the optimum reaction conditions for achiveing selectivity for monoiodination.